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Medvedev sees off De Minaur to boost ATP Finals bid
The Russian, who lost his first group-stage match to Taylor Fritz, overpowered De Minaur in Turin to win 6-2, 6-4 and leave his opponent on the brink of elimination.
Australian De Minaur will be knocked out with a match to spare if the other tie in the Ilie Nastase Group between Jannik Sinner and Fritz goes to three sets later on Tuesday.
Medvedev, who lifted the title in 2020, did not face a single break point and broke De Minaur's serve three times.
The fourth seed will next face world number one and title favourite Sinner on Thursday.